| 399 |  Jenne-Lee Steyl Rachel Joffe | 30-39 | 05:43 | |
| 402 |  Gorata chikadzi Ramasuswana Gouta Leneh Kamanga | 30-39 | 05:48 | |
| 402 | Anele Mkuzo Luleka Mkuzo | 30-39 | 05:48 | |
| 402 | Gugulethu Mohlabe Nokuthula Manana | 30-39 | 05:48 | |
| 402 | Rosie Claire Campbell  Tamara Sutila | 50-59 | 05:48 | |
| 406 | Masego Mentor Nthabiseng Buyile Mentor | 30-39 | 05:49 | |
| 407 | Abulele Nogaya Ntando Nsuntsha | 16-29 | 05:53 | |
| 408 | Mpuleng Molefi Nosipho Moyo | 30-39 | 05:54 | |
| 409 | Amanda Ndlangisa Thato Nyama | 30-39 | 05:55 | |
| 410 | Musa Nhlapo Noluthando Nhlapo | 16-29 | 05:56 | |
| 410 | Melissa Papastefanou Nicole Krynauw | 30-39 | 05:56 | |
| 412 | Murendeni Nemaitoni Orapetswe Mokgatle | 30-39 | 06:01 | |
| 413 | Minette Poulter Natalie Christie | 30-39 | 06:05 | |
| 414 | Hervine Muya Noemi Muya | 16-29 | 06:15 | |
| 415 | Kelebogile Tau Mokgethwa Bambo | 16-29 | 06:19 | |
| 415 | Ncala Noma Nontokozo Mlaba | 30-39 | 06:19 | |
| 415 | Boniswa Ndlovu Londi Sibisi | 40-49 | 06:19 | |
| 418 | Kamogelo Poole Thulebona Mhlanga | 30-39 | 06:20 | |
| 419 | Masego Bethel Tuduetso Molimi | 40-49 | 06:26 | |
| 420 | Anele Mkhize Nonhlanhla Hlatshwayo | 40-49 | 07:51 | |
| 421 | Brenda Saaiman Mareli Müller | 40-49 | 07:59 | |
