| 1 |  Ghani Khelif Manon Antunes | 16-29 | 03:35 | |
| 2 |  Esther Jimenez Palomera Jose Julian Rueda Osuna | 30-39 | 03:37 | |
| 3 |  Ana Carvalho David Queiroz | 16-29 | 03:41 | |
| 3 | David Madina Veronica Sanchez Benitez | 40-49 | 03:41 | |
| 5 | Francisco Javier Lozano Flores Lozano Rossana Spagnuolo | 30-39 | 03:43 | |
| 6 | Ania Arregi Celayeta Ekain Nogueira | 16-29 | 03:44 | |
| 6 | Idoia Olabarrieta Arranz Mikel Saez De Lafuente Rubio | 30-39 | 03:44 | |
| 6 | Gregorio Rodríguez Márquez Uxue Irigoyen Bravo | 16-29 | 03:44 | |
| 6 | Eider Cantero Mikel Alonso Reta | 16-29 | 03:44 | |
| 6 | Cristian Rosal Surez Míriam Turbett Álvarez | 16-29 | 03:44 | |
| 11 | Irina Zakharova Mikhail Skurikhin | 30-39 | 03:45 | |
| 11 | Diego Roces Surez Jennifer Carla Fernández Viña | 16-29 | 03:45 | |
| 13 | Rafa Ten Fernández Sandra Martínez | 16-29 | 03:46 | |
| 14 |  Holly Price Joshua Berg | 16-29 | 03:47 | |
| 14 | Aitor Aut Alarcón Maria Lourdes Diez Fuentes | 30-39 | 03:47 | |
| 16 | Brice Ablasou Sandra CHETANEAU | 40-49 | 03:48 | |
| 16 | Rita Rebelo Telmo Pinho | 30-39 | 03:48 | |
| 16 | Benjamin Cloarec Camille Cayot | 16-29 | 03:48 | |
| 19 | Bernardo José Bustos Martínez Cristina Obrador Ramos | 30-39 | 03:49 | |
| 19 | Jonathan Aras Pilar Martinez Ojeda | 30-39 | 03:49 | |
| 19 | Cristina Balandrón Val Félix Pascual Santamaría | 16-29 | 03:49 | |
| 22 | Adrián Benito Toledo Natalia Pinilla | 16-29 | 03:50 | |
| 22 | Emi Mellinas Ricky Di Marco | 30-39 | 03:50 | |
| 22 | Aitor Velasco Durand Ane Ormaetxea González | 16-29 | 03:50 | |
| 25 | Joel Vázquez Medina Uxue Sordo Nespral | 16-29 | 03:51 | |
| 26 | João Leitão Tânia Cruz | 30-39 | 03:52 | |
| 26 | Alba Moreno Miralles Davide Oneda | 16-29 | 03:52 | |
| 26 | António Ferreira Sara Neves | 16-29 | 03:52 | |
| 26 | Ricardo Venegas González Rosa Martinez Martinez | 30-39 | 03:52 | |
| 26 | Carmen Hernandez Estefano Iñigo Barturen Val | 30-39 | 03:52 | |
| 31 | Amaia Malaina Celada Kyle Rimmer-Greaves | 30-39 | 03:53 | |
| 31 | Diego Fernandez Requejo Sara Villa Gonzalez | 30-39 | 03:53 | |
| 33 | Oscar Cao Alvarez Sara Virginia Isidro Read | 30-39 | 03:54 | |
| 34 | Elena Olalla Iborras Pere Joan Frau Morey | 16-29 | 03:55 | |
| 34 | Euken Ballester Arrieta Nuria Alonso Ordas | 30-39 | 03:55 | |
| 36 | Mathilde Delorme Ricard Maudsley | 16-29 | 03:56 | |
| 36 | Andreu Massot Isern Bàrbara Amengual Frau | 16-29 | 03:56 | |
| 36 | Alberto Chaves Camino Natalia Basanta Fouz | 30-39 | 03:56 | |
| 36 | Guillermo Rey-Baltar Galindez Sandra Perez García | 30-39 | 03:56 | |
| 40 | Maite Salgado Sergio Monteagudo | 40-49 | 03:57 | |
| 40 | Gema Valle Murias Moya Ruben Coto Hernandez | 40-49 | 03:57 | |
| 40 | Álvaro Alonso Coll Cristina Mut Cerón | 30-39 | 03:57 | |
| 40 | Maitena Masip Rodrigo Ramirez | 30-39 | 03:57 | |
| 40 | Arantxa Prado Santiago Diego Chas Vázquez | 40-49 | 03:57 | |
| 45 | Jero Bonzom Bermejo Miriam Rodriguez Ibarra | 30-39 | 03:58 | |
| 45 | Cátia Paulino Duarte Alves | 16-29 | 03:58 | |
| 45 | Isabel Ruiz Pérez Miguel Angel Sanchez Jiménez | 40-49 | 03:58 | |
| 48 | Andrea Caramés Juez Eduardo Alonso Martínez | 30-39 | 03:59 | |
| 49 | Diana Lopez Centeno Haritz Diaz Mugica | 16-29 | 04:00 | |
| 49 | Aitor Lizarazu Hormilla Janire Anaut Moral | 16-29 | 04:00 | |
| 49 | Chantal Presas Fernandez David Gonzalez Exposito | 40-49 | 04:00 | |
| 52 | Almudena Carvajal Noriega Iban Barrutia Uralde | 30-39 | 04:01 | |
| 52 | Paula La Orden Mateu Rinson Lopez Ledesma | 30-39 | 04:01 | |
| 54 | Giacomo Colombo Marta Maria Real Amengual | 30-39 | 04:02 | |
| 54 | Aritz Iginitz Oyarzabal Maitane Lopez Gonzalez | 30-39 | 04:02 | |
| 54 | Aitor Gonzalez Lopez Andrea Azkune | 16-29 | 04:02 | |
| 54 | Idoia Eceiza Imanol Gorrotxategi Sangroniz | 40-49 | 04:02 | |
| 54 | Alejandro Regalado Fernandez Lucia De Querol Vazquez | 30-39 | 04:02 | |
| 59 | Maria Petrou-Dunn Mark Crooks | 30-39 | 04:03 | |
| 59 | Daniel Harto Lozano Leire Aguirregabiria Cidón | 16-29 | 04:03 | |
| 61 | Samuel Viera Tolosa Yadira Perez Jimenez | 30-39 | 04:04 | |
| 61 | Imanol Rodriguez Municio Sanna Hassanaine | 40-49 | 04:04 | |
| 61 | Carla Carpio Estanis Carpio | 16-29 | 04:04 | |
| 61 | Andreia Amaro Nuno Carvalho | 30-39 | 04:04 | |
| 61 | Asier Aboitiz Garbayo Begoña Maeztu Fernndez | 30-39 | 04:04 | |
| 61 | Alba Lopez Ramos Eneko Lira Gómez | 30-39 | 04:04 | |
| 67 | Andrea Molina Giménez Javier Giner Tobias | 16-29 | 04:05 | |
| 67 | Cristina Dominguez Blasco Javier García Hernandez | 40-49 | 04:05 | |
| 67 | Mamen Cantero Boy Marcos Falcon Falcon | 30-39 | 04:05 | |
| 67 | Blanco Saez De Lafuente Carrasco Pérez | 30-39 | 04:05 | |
| 67 | Luna Campos Troyano Victor Santacruz Postigo | 30-39 | 04:05 | |
| 67 | Aingeru Eguia Ortiz Itziar Polo Iturregui | 30-39 | 04:05 | |
| 73 | Juan Jesús Cubillo Rodríguez Maria Núñez Caloto | 50-59 | 04:06 | |
| 73 | June Ibarguen Martiarena Mikel Zurutuza Tovar | 16-29 | 04:06 | |
| 73 | Alvaro Carrasco Lopez De Ochoa Leire Mendoza Solozabal | 16-29 | 04:06 | |
| 76 | Alvaro Gomez San Emeterio Lucia Martinez Martinez | 30-39 | 04:07 | |
| 76 | Erika Benitez Rodriguez Gorka Zumeta Urtizberea | 16-29 | 04:07 | |
| 76 | Abel Etxaniz Etxeberria Beronika Montero Gordillo | 40-49 | 04:07 | |
| 76 | Claudia Antepara De La Sota Iñigo Ubierna Vivanco | 16-29 | 04:07 | |
| 76 | Beatriz Guede Brito Gabriel López Martínez-Fortún | 30-39 | 04:07 | |
| 81 | Ainize Lizarralde Ugalde Jon Imanol Gaspar Pintado | 16-29 | 04:08 | |
| 81 | Bruno Ramos Júlia Nunes | 30-39 | 04:08 | |
| 81 | Ana Isabel Íñigo Sanchez Jorge Villa Serrano | 30-39 | 04:08 | |
| 81 | Imanol Ribera Gutierrez Maite Ribera Gutierrez | 16-29 | 04:08 | |
| 81 | Ainhize Rivadas Jiménez Ander Villanueva Arroyo | 16-29 | 04:08 | |
| 81 | Amaia Zabala Arriola Borja Pérez Zulaica | 40-49 | 04:08 | |
| 87 | Gorka Zubizarreta Calvo Irati Beorlegi | 16-29 | 04:09 | |
| 87 | Jorge Diaz Rodriguez Sheila Martinez Tahoces | 40-49 | 04:09 | |
| 87 | José Francisco García Carrasco Patricia Durán Sánchez | 30-39 | 04:09 | |
| 90 | Alberto Berrocal Arevalo  Silvia Czaja | 30-39 | 04:10 | |
| 90 | Ainhoa Garnika Rodriguez Jon Garnika Rodriguez | 40-49 | 04:10 | |
| 90 | Asier Barato Salor Nerea Sanz Guinea | 30-39 | 04:10 | |
| 90 | Alex Crende Mireia Lartategi | 30-39 | 04:10 | |
| 90 | Aitor Iriondo Raquel Rodríguez | 16-29 | 04:10 | |
| 90 | Dejan Pureta Sabine Pureta | 40-49 | 04:10 | |
| 96 | Inês Paulino Marco Moura | 40-49 | 04:11 | |
| 96 | Alegría Gracia Sánchez Juan Carlos Arinas Salazar | 16-29 | 04:11 | |
| 96 | Lúcia Silva Mario Porfirio | 40-49 | 04:11 | |
| 96 | Alfredo Ruesgas Lambarri Karmele Herrero | 40-49 | 04:11 | |
| 96 | Antoni Pizá Bestard Munia Pérez Castañer | 30-39 | 04:11 | |
